材料名称：MIL-53(Fe)
其他名称：NA
CAS：764608-47-1
其他名称：NA
CAS：764608-47-1
结构信息
| 单位分子式 | C8H4O5Fe | 单位分子量 | 235.96 | ||
| 配位金属 | Fe | 配体 | 对苯二甲酸（CAS：100-21-0） | ||
| 孔径 | 孔容 | ||||
| 比表面 | N2 BET比表面 无法测出 | ||||
| 模拟结构 |   |
||||
产品性状
| 产品形貌 | 黄褐色粉末 Orange Powder |
 |
||
| 粒径 | 300-600nm | |||
稳定性
1) MIL-53(Fe)在空气中稳定，在水溶液及酸性条件下中稳定
2) 高热稳定性、热分解温度大于300℃
2) 高热稳定性、热分解温度大于300℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前150度（真空）烘箱活化3小时
2) 建议使用前150度（真空）烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 气体（如二氧化碳）和污染物吸附
2) 作为路易斯酸催化剂具有良好的催化性能
2) 作为路易斯酸催化剂具有良好的催化性能
表征图谱
参考文献
1）T. R. Whitfield, X. Q. Wang, L. M. Liu, A. J. Jacobson, Solid State Sci 2005, 7, 1096-1103, DOI: 10.1016/j.solidstatesciences.2005.03.007 ; Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions；
2）Dengke Wang, Renkun Huang, Wenjun Liu, Dengrong Sun, Zhaohui Li; ACS Catalysis, 2014, 4, 4254−4260; DOI: 10.1021/cs501169t ; Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways【文献解读】；
2）Dengke Wang, Renkun Huang, Wenjun Liu, Dengrong Sun, Zhaohui Li; ACS Catalysis, 2014, 4, 4254−4260; DOI: 10.1021/cs501169t ; Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways【文献解读】；
3) Dongbo Wang, Feiyue Jia, Hou Wang, Fei Chen, Ying Fang, Wenbo Dong, Guangming Zeng, Xiaoming Li, Qi Yang, Xingzhong Yuan. Journal of Colloid and Interface Science, 2018, volume, issue. DOI：10.1016/j.jcis.2018.02.067. Simultaneously efficient adsorption and photocatalytic degradation of tetracycline by Fe-based MOFs.【文献解读】；
4）Fei-Long Li, Qi Shao, Xiaoqing Huang, Jian-Ping Lang. Angewandte Chemie International Edition, 2018, 57, 1888-1892. DOI：0.1002/anie.201711376. Nanoscale Trimetallic Metal–Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis.【文献解读】；
5）Yaowen Gao, Simiao Li, Yixi Li, Linyu Yao, Hui Zhang. Applied Catalysis B: Environmental, 2016, volume, issue. DOI:10.1016/j.apcatb.2016.09.005. Accelerated photocatalytic degradation of organic pollutant over metal-organic framework MIL-53(Fe) under visible LED light mediated by persulfate.【文献解读】;
6) Lomig Hamon, Christian Serre, Thomas Devic, Thierry Loiseau, Franck Millange, Gérard Férey, Guy De Weireld; Journal of the American Chemical Society, 2009, 131, 25; DOI：10.1021/ja901587t; Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature.【文献解读】;
7) Cheng-Xiong Yang, Hu-Bo Ren, Xiu-Ping Yan; Anal. Chem. 2013, 85, 15, 7441–7446; DOI: 10.1021/ac401387z; Fluorescent Metal−Organic Framework MIL-53(Al) for Highly Selective and Sensitive Detection of Fe3+ in Aqueous Solution.【文献解读】;
8）Weiping Xiong, Guangming Zeng, Zhaohui Yang, Yaoyu Zhou, Chen Zhang, Min Cheng, Yang Liu, Liang Hu, Jia Wan, Chengyun Zhou, Rui Xu, Xin Li.; Science of the Total Environment, 2018, 633, 1302-1311; DOI：10.1016/j.scitotenv.2018.01.249; Adsorption of tetracycline antibiotics from aqueous solutions on nanocomposite multi-walled carbon nanotube functionalized MIL-53(Fe) as new adsorbent.【文献解读】
购销咨询 
