材料名称：ZIF-8
其他名称：MAF-4 ; 2-Methylimidazole zinc salt ; BasoLite Z1200
CAS：59061-53-9
其他名称：MAF-4 ; 2-Methylimidazole zinc salt ; BasoLite Z1200
CAS：59061-53-9
结构信息
| 单位分子式 | C8H10N4Zn | 单位分子量 | 227.5818 | ||
| 配位金属 | Zn | 配体 | 2-甲基咪唑（CAS：693-98-1） | ||
| 孔径 | 0.34nm; 1.1nm | 孔容 | 0.66 cm3/g | ||
| 比表面 | BET比表面1500 m2/g | ||||
| 模拟结构 |    |
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产品性状
| 产品形貌 | 类白色粉末 Off-white Powder |
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| 粒径 | 200nm; 500nm; 1um; 5um | |||
稳定性
1) 空气中持久稳定，水溶液和强碱溶液中稳定；酸性条件下不稳定
2) 高热稳定性、热分解温度大于400℃
2) 高热稳定性、热分解温度大于400℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 气体吸附测试前，建议使用前120度（真空）烘箱活化12小时
2) 气体吸附测试前，建议使用前120度（真空）烘箱活化12小时
其他特性
荧光:NA
应用领域
1) 储气材料和吸附材料
2) 可作为药物载体进行药物吸附和缓释
2) 可作为药物载体进行药物吸附和缓释
表征图谱
参考文献
1) Huang, Xiao-Chun; Lin, Yan-Yong; Zhang, Jie-Peng; Chen, Xiao-Ming; Angew. Chem. Int. Ed. 2006, 45, 1557-1559, DOI: 10.1002/anie.200503778 ; Ligand-directed strategy for zeolite-type metal-organic frameworks: zinc(II) imidazolates with unusual zeolitic topologies
2) Park, Kyo Sung; Ni, Zheng; Cote, Adrien P.; Choi, Jae Yong; Huang, Rudan; Uribe-Romo, Fernando J.; Chae, Hee K.; O'Keeffe, Michael; Yaghi, Omar M.; Proc. Natl. Acad. Sci. USA 2006, 103, 10186-10191, DOI: 10.1073/pnas.0602439103 ; Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
3) Liu, Chang; Tong, Yu-Long; Yu, Xiao-Qing; Shen, Haixia; Zhu, Zhijie; Li, Qing; Chen, Su; ACS Appl. Mater. Interfaces 2020, 12, 2, 2816–2825, DOI: 10.1021/acsami.9b18012 ; MOF-Based Photonic Crystal Film toward Separation of Organic Dyes;
4) Guang Lu, Shaozhou Li, Zhen Guo, Omar K. Farha, Brad G. Hauser, Xiaoying Qi, Yi Wang, Xin Wang, Sanyang Han, Xiaogang Liu, Joseph S. DuChene, Hua Zhang, Qichun Zhang, Xiaodong Chen, Jan Ma, Say Chye Joachim Loo, Wei D. Wei, Yanhui Yang, Joseph T. Hupp, Fengwei Huo; NATURE CHEMISTRY, 2012, 4; DOI：10.1038/nchem.1272; Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation【文献解读】;
5) Yichang Pan, Yunyang Liu, Gaofeng Zeng, Lan Zhao, Zhiping Lai*;ChemComm, 2011, 47, 2071–2073; DOI：10.1039/c0cc05002d; Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system【文献解读】;
6) Helge Bux, Fangyi Liang, Yanshuo Li, Janosch Cravillon, Michael Wiebcke, Ju¨rgen Caro; J. AM. CHEM. SOC., 2009, 131, 44; DOI：10.1021/ja907359t; Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis【文献解读】;
7) D. Fairen-Jimenez, S. A. Moggach, M. T. Wharmby, P. A. Wright, S. Parsons, T. Düren; Journal of the American Chemical Society, 2011, 133, 8900–8902; DOI：10.1021/ja202154j; Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations【文献解读】;
8) Janosch Cravillon, Roman Nayuk, Sergej Springer, Armin Feldhoff, Klaus Huber, Michael Wiebcke; Chemistry of Materials, 2011, 23, 2130-2141; DOI：10.1021/cm103571y; Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering【文献解读】;
9) Guang Lu and Joseph T. Hupp*; J. AM. CHEM. SOC., 2010, 132, 23, 7832-7833; DOI：10.1021/ja101415b; Metal-Organic Frameworks as Sensors: A ZIF-8 Based Fabry-Pérot Device as a Selective Sensor for Chemical Vapors and Gases【文献解读】;
10) Kui Shen, Lei Zhang, Xiaodong Chen, Lingmei Liu, Daliang Zhang, Yu Han, Junying Chen, Jilan Long, Rafael Luque, Yingwei Li, Banglin Chen; Science, 2018, 359, 6372; DOI ：10.1126/science.aao3403; Ordered macro-microporous metal-organic framework single crystals【文献解读】;
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