材料名称：SIFSIX-2-Cu-i
其他名称：[Cu(dpa)2SiF6-i]
CAS：726124-20-5
其他名称：[Cu(dpa)2SiF6-i]
CAS：726124-20-5
结构信息
| 单位分子式 | C24H8N4F6SiCu | 单位分子量 | 557.97 | ||
| 配位金属 | Cu | 配体 |
1,2-二吡啶乙炔 1,2-bis(4-pyridyl)ethyne (CAS：73564-69-9) |
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| 孔径 | ~0.5nm | 孔容 | 0.2 cm3/g | ||
| 比表面 | NA | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 灰紫色粉末 Grey Purple Powders |
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| 粒径 | 不规则块状 | |||
稳定性
1) SIFSIX-2-Cu-i在潮湿空气中稳定，在水和乙醇中稳定
2) 热分解温度大于300℃
2) 热分解温度大于300℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前室温真空烘箱活化3小时
2) 建议使用前室温真空烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 气体吸附与分离（如二氧化碳、二氧化硫等）
2) 工业气体分离（乙烷/乙烯）
2) 工业气体分离（乙烷/乙烯）
表征图谱
参考文献
1) Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.; Cairns, Amy J.; Luebke, Ryan; Forrest, Katherine; Pham, Tony; Ma, Shengqian; Space, Brian; Wojtas, Lukasz; Eddaoudi, Mohamed; Zaworotko, Michael J.; Nature 2013), 495(7439), 80-84, DOI: 10.1038/nature11893 ; Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation【文献解读】；
2) Qian, Siheng; Xia, Ling; Yang, Lifeng; Wang, Xiaobing; Suo, Xian; Cui, Xili; Xing, Huabin From Journal of Membrane Science (2020)611, 118329, DOI: 10.1016/j.memsci.2020.118329 ; Defect-free mixed-matrix membranes consisting of anion-pillared metal-organic frameworks and poly(ionic liquid)s for separation of acetylene from ethylene；
3）Xili Cui, Kaijie Chen, Huabin Xing, Qiwei Yang, Rajamani Krishna, Zongbi Bao, Hui Wu, Wei Zhou, Xinglong Dong, Yu Han, Bin Li, Qilong Ren, Michael J. Zaworotko, Banglin Chen. Science, 2016, 353, 6295, 141-145. DOI:10.1126/science.aaf2458. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene【文献解读】;
4) Yang, L. F., Cui, X. L., Yang, Q. W., Qian, S. H., Wu, H., Bao, Z. B., Zhang, Z. G., Ren, Q. L., Zhou, W., Chen, B., Xing, H. B. (2018). Advanced Materials, 30(1), 1705374. DOI: 10.1002/adma.201705374; A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials【文献解读】；
5) Jieyi Zheng, Xili Cui, Qiwei Yang, Qilong Ren, Yiwen Yang, Huabin Xing; Chemical Engineering Journal, 2018, 354, 1075-1082; DOI：10.1016/j.cej.2018.08.119; Shaping of ultrahigh-loading MOF pellet with a strongly anti-tearing binder for gas separation and storage【文献解读】;
6）Xili Cui, Qiwei Yang, Lifeng Yang, Rajamani Krishna, Zhiguo Zhang, Zongbi Bao, Hui Wu, Qilong Ren, Wei Zhou, Banglin Chen, Huabin Xing; Advanced Materials, 2017, 29, 1606929; DOI：10.1002/adma.201606929; Ultrahigh and Selective SO₂ Uptake in Inorganic Anion-Pillared Hybrid Porous Materials【文献解读】;
7) Daniel O’Nolan, Amrit Kumar, Michael J. Zaworotko*; Journal of the American Chemical Society, 2017, 139, 8508-8513; DOI：10.1021/jacs.7b01682; Water Vapor Sorption in Hybrid Pillared Square Grid Materials【文献解读】;
8) Katherine A. Forrest, Tony Pham, Brian Space;CrystEngComm, 2017, 19, 3338-3347;DOI ：10.1039/c7ce00594f;Comparing the mechanism and energetics of CO₂ sorption in the SIFSIX series【文献解读】；
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