材料名称：NH2-MIL-53(Al)
其他名称：NA
CAS：1134360-62-5
其他名称：NA
CAS：1134360-62-5
结构信息
| 单位分子式 | C8H5NO5Al | 单位分子量 | 222.11 | ||
| 配位金属 | Al | 配体 | 2-氨基对苯二甲酸（CAS：10312-55-7） | ||
| 孔径 | 0.8nm; 1.3nm | 孔容 | 0.5 cm3/g | ||
| 比表面 | BET比表面 950 m2/g, | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 白色粉末 White Powder |
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| 粒径 | 100nm 或 500nm | |||
稳定性
1) NH2-MIL-53(Al)在空气中较稳定，在水溶液和碱性条件较为稳定
2）高热稳定性、热分解温度大于400℃
2）高热稳定性、热分解温度大于400℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前150度（真空）烘箱活化3小时
2) 建议使用前150度（真空）烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 气体（如二氧化碳）和污染物吸附
2) 作为路易斯酸催化剂
2) 作为路易斯酸催化剂
表征图谱
参考文献
1) Ahnfeldt, T., Gunzelmann, D., Loiseau, T., Hirsemann, D., Senker, J., Férey, G., Stock, N. Inorg. Chem.2009,48,7, 3057-3064; DOI: 10.1021/ic8023265 ; Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology【文献解读】；
2) Gascon, J.; Aktay, U.; Hernandez-Alonso, Maria D.; van K., Gerard P. M.; Kapteijn, F., Journal of Catalysis 2009, 261 (1), 75-87; DOI: 10.1016/j.jcat.2008.11.010 ; Amino-based metal-organic frameworks as stable, highly active basic catalysts;
2) Gascon, J.; Aktay, U.; Hernandez-Alonso, Maria D.; van K., Gerard P. M.; Kapteijn, F., Journal of Catalysis 2009, 261 (1), 75-87; DOI: 10.1016/j.jcat.2008.11.010 ; Amino-based metal-organic frameworks as stable, highly active basic catalysts;
3) Meng Jin, Zhao-Li Mou, Rui-Ling Zhang, Si-Si Liang, Zhi-Qi Zhang. Biosensors and Bioelectronics, 2017, 88, 447-454. DOI: 10.1016/j.bios.2016.12.022. An efficient ratiometric fluorescence sensor based on metal-organic frameworks and quantum dots for highly selective detection of 6-mercaptopurine.【文献解读】;
4) Joseph G. Nguyen, Seth M. Cohen*;J. AM. CHEM. SOC., 2010, 132, 13; DOI：10.1021/ja100900c; Moisture-Resistant and Superhydrophobic Metal-Organic Frameworks Obtained via Postsynthetic Modification【文献解读】；
5) Wenchang Yin, Cheng-an Tao, Xiaorong Zou, Fang Wang, Tianlian Qu, Jianfang Wang; Nanomaterials, 2017, 7, 242; DOI：10.3390/nano7090242; The Tuning of Optical Properties of Nanoscale MOFs-Based Thin Film through Post-Modification【文献解读】；
6) Beatriz Zornoza, Alberto Martinez-Joaristi, Pablo Serra-Crespo, Carlos Tellez, Joaquin Coronas, Jorge Gascon, Freek Kapteijn; Chemical Communications, 2011, 47, 9522-9524; DOI ：10.1039/c1cc13431k; Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO₂ from CH₄ at elevated pressures【文献解读】；
7）Karen Leus, Thomas Bogaerts, Jeroen De Decker, Hannes Depauw, Kevin Hendrickx, Henk Vrielinck, Veronique Van Speybroeck, Pascal Van Der Voort; Microporous and Mesoporous Materials, 2016, 220; DOI：10.1016/j.micromeso.2015.11.055; Systematic study of the chemical and hydrothermal stability of selected “stable” Metal Organic Frameworks【文献解读】；
8）Chen Li, Zhenhu Xiong, Jinmiao Zhang, Chunsheng Wu; Journal of Chemical & Engineering Data, 2015, 60, 3414−3422; DOI：10.1021/acs.jced.5b00692; The Strengthening Role of the Amino Group in Metal−Organic Framework MIL-53 (Al) for Methylene Blue and Malachite Green Dye Adsorption【文献解读】；
9）Manuel Sánchez-Sánchez, Negash Getachew, Kenya Díaz, Manuel Díaz-García, Yonas Chebudeb, Isabel Díaz; Green Chem., 2015, 17, 1500-1509; DOI：10.1039/c4gc01861c; Synthesis of metal–organic frameworks in water at room temperature: salts as linker sources【文献解读】；
10）Chunhua Li, Jianlong Wang, Li Zhu, Weixia Yang, Xie He, Sheliang Zhao, Xiaoshuo Zhang, Wenzhi Tang, Tianli Yue, Zhonghong Li; Journal of Agricultural and Food Chemistry, 2019, 67, 1277−1283; DOI：10.1021/acs.jafc.8b06253; Amino-Functionalized Al−MOF for Fluorescent Detection of Tetracyclines in Milk【文献解读】；
11）Alberto Martinez Joaristi, Jana Juan-Alcaniz, Pablo Serra-Crespo, Freek Kapteijn, Jorge Gascon;Cryst. Growth Des., 2012, 12, 3489-3498; DOI：10.1021/cg300552w; Electrochemical Synthesis of Some Archetypical Zn²⁺, Cu²⁺, and Al³⁺ Metal Organic Frameworks【文献解读】；
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