材料名称：MOF-74(Mg)
其他名称：Mg-MOF-74; Mg-DOBDC; CPO-27(Mg); Mg2(dhtp)
CAS：1174268-74-6
其他名称：Mg-MOF-74; Mg-DOBDC; CPO-27(Mg); Mg2(dhtp)
CAS：1174268-74-6
结构信息
| 单位分子式 | C8H4O8Mg2 | 单位分子量 | 276.72256 | ||
| 配位金属 | Mg | 配体 | 2,5-二羟基对苯二甲酸 (CAS: 610-92-4) | ||
| 孔径 | 1.2 nm 垂直孔道 | 孔容 | 0.65cm3/g | ||
| 比表面 | BET比表面 1100 m2/g | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 黄色粉末 Yellow Powders |  |
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| 粒径 | 3-5um 不规则块状颗粒 | |||
稳定性
1) MOF-74在密闭干燥条件下稳定数周；在空气中尤其是潮湿气氛中（湿度>10%）易吸湿分解；
2) 高热稳定性、热分解温度大于450℃
2) 高热稳定性、热分解温度大于450℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前150度（真空）烘箱活化6小时
2) 建议使用前150度（真空）烘箱活化6小时
其他特性
荧光:NA
应用领域
1) 储气（如二氧化碳、甲烷）材料和吸附材料
2) MOF-74在水溶液中分解，可作为药物载体进行药物吸附和缓释
2) MOF-74在水溶液中分解，可作为药物载体进行药物吸附和缓释
表征图谱
参考文献
1）J.K. Nathaniel, L. Rosi, Eddaoudi Mohamed, Banglin Chen, Michael O'Keeffe, Omar M. Yaghi, J. Am. Chem. Soc. 2005, 127, 1504–1518, DOI: 10.1021/ja045123o ; Rod packings and Metal−Organic frameworks constructed from rod-shaped secondary building units
2) Dietzel, Pascal D. C.; Blom, Richard; Fjellvaag, Helmer; European Journal of Inorganic Chemistry 2008, 23, 3624-3632, DOI: 10.1002/ejic.200701284 ; Base-Induced Formation of Two Magnesium Metal-Organic Framework Compounds with a Bifunctional Tetratopic Ligand;
3) Yabing He, Rajamani Krishna, Banglin Chen; Energy & Environmental Science, 2012, 5, 9107-9120; DOI：10.1039/c2ee22858k; Metal-Organic Frameworks with Potential for Energy-Efficient Adsorptive Separation of Light Hydrocarbons【文献解读】；
4）Da-Ae Yang, Hye-Young Cho, Jun Kim, Seung-Tae Yang, Wha-Seung Ahn; Energy & Environmental Science, 2012, 5, 6465-6473; DOI：10.1039/c1ee02234b; CO₂ capture and conversion using Mg-MOF-74 prepared by a sonochemical method【文献解读】；
5）Paul M. Schoenecker, Cantwell G. Carson, Himanshu Jasuja, Christine J. J. Flemming, Krista S. Walton; Industrial & Engineering Chemistry Research, 2012, 51, 6513-6519; DOI：10.1021/ie202325p; Effect of Water Adsorption on Retention of Structure and Surface Area of Metal−Organic Frameworks【文献解读】；
6）Jarad A. Mason, Kenji Sumida, Zoey R. Herm, Rajamani Krishna, Jeffrey R. Long;Energy & Environmental Science, 2011, 4, 3030-3040; DOI：10.1039/c1ee01720a; Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption【文献解读】；
7）Youn-Sang Bae, Chang Yeon Lee, Ki Chul Kim, Omar K. Farha, Peter Nickias, Joseph T. Hupp, SonBinh T. Nguyen, Randall Q. Snurr; Angewandte Chemie International Edition, 2012, 51, 1857-1860; DOI：10.1002/anie.201107534; High Propene/Propane Selectivity in Isostructural Metal–Organic Frameworks with High Densities of Open Metal Sites【文献解读】；
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