材料名称：PCN-224(H)
其他名称：NA
CAS：1476810-88-4
其他名称：NA
CAS：1476810-88-4
结构信息
| 单位分子式 | C144H72N12O64Zr15+2 | 单位分子量 | 4362.51448 | ||
| 配位金属 | Zr | 配体 | 四羧基苯基卟啉 H2TCPP（CAS：14609-54-2） | ||
| 孔径 | 1.9nm | 孔容 | 1.59 cm3/g | ||
| 比表面 | BET比表面2600 m2/g | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 红棕色粉末 Reddish Brown Powder |
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| 粒径 | ||||
稳定性
1) 空气中持久稳定，水溶液和酸性-弱碱溶液中较为稳定（PH 0-11）
2) 热分解温度约>400℃
2) 热分解温度约>400℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前80度（真空）烘箱活化12小时
2) 建议使用前80度（真空）烘箱活化12小时
其他特性
荧光: 激发波长430nm，发射波长652nm，显示红光
应用领域
1) PCN-224(Co)对CO2 /环氧丙烷偶联反应表现出高催化活性
2) PCN-224 在室温和100kPa下对C3H8展现出高达8.25mmol/g吸附量
2) PCN-224 在室温和100kPa下对C3H8展现出高达8.25mmol/g吸附量
3) PCN-224能够细胞成像并能作为光敏剂对肿瘤进行治疗
4) PCN-224能够对Hg离子和硝基化合物进行传感检测，PCN-224(Pt)能够对氧气传感检测
表征图谱
参考文献
1) D. Feng, W.-C. Chung, Z. Wei, Z.-Y. Gu, H.-L. Jiang, Y.-P. Chen, D. J. Darensbourg, and H.-C. Zhou, J. Am. Chem. Soc. 2013, 135, 17105-17110, DOI: 10.1021/ja408084j ; Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination【文献解读】;
2) J. Park, Q. Jiang, D. Feng, L. Mao, and H.-C. Zhou, J. Am. Chem. Soc. 2016, 138, 3518-3525, DOI: 10.1021/jacs.6b00007 ; Size-Controlled Synthesis of Porphyrinic Metal–Organic Framework and Functionalization for Targeted Photodynamic Therapy;
3) Shi-Ying Li, Hong Cheng, Bo-Ru Xie, Wen-Xiu Qiu, Jing-Yue Zeng, Chu-Xin Li, Shuang-Shuang Wan, Lu Zhang, Wen-Long Liu, Xian-Zheng Zhang*;ACS Nano, 2017, 11, 7006−7018;DOI：10.1021/acsnano.7b02533;Cancer Cell Membrane Camouflaged Cascade Bioreactor for Cancer Targeted Starvation and Photodynamic Therapy【文献解读】;
4）Donglin Han, Yajing Han, Jun Li, Xiangmei Liu, Kelvin Wai Kwok Yeung, Yufeng Zheng, Zhenduo Cui, Xianjin Yang, Yanqin Liang, Zhaoyang Li, Shengli Zhu, Xubo Yuan, Xiaobo Feng, Cao Yang, Shuilin Wu;Applied Catalysis B: Environmental, 2020, 261, 118248;DOI：10.1016/j.apcatb.2019.118248;Enhanced photocatalytic activity and photothermal effects of cu-doped metal-organic frameworks for rapid treatment of bacteria-infected wounds【文献解读】;
5）Guangyao Zhai, Yuanyuan Liu, Longfei Lei, Jiajia Wang, Zeyan Wang, Zhaoke Zheng, Peng Wang, Hefeng Cheng, Ying Dai, Baibiao Huang;ACS Catalysis, 2021, 11, 1988-1994; DOI：10.1021/acscatal.0c05145; Light-Promoted CO₂ Conversion from Epoxides to Cyclic Carbonates at Ambient Conditions over a Bi-Based Metal–Organic Framework【文献解读】;
6）Kibeom Kim, Sungmin Lee, Eunji Jin, L. Palanikumar, Jeong Hyeon Lee, Jin Chul Kim, Jung Seung Nam, Batakrishna Jana, Tae-Hyuk Kwon, Sang Kyu Kwak, Wonyoung Choe, Ja-Hyoung Ryu;ACS Applied Materials & Interfaces, 2019, 11, 27512-27520;DOI：10.1021/acsami.9b05736;MOF × Biopolymer: Collaborative Combination of Metal−Organic Framework and Biopolymer for Advanced Anticancer Therapy【文献解读】;
7) Jiuhai Wang, Yadi Fan, Youhua Tan, Xin Zhao, Yu Zhang, Changming Cheng, Mo Yang;ACS Applied Materials & Interfaces, 2018, 10, 36615−36621;DOI：10.1021/acsami.8b15452;Porphyrinic Metal-organic Framework PCN224 Nanoparticles for Near-IR Induced Attenuation of Aggregation and Neurotoxicity of Alzheimer’s Amyloid-β Peptide【文献解读】;
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