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ZIF-67(Co)

ZIF-67

CAS NO.:46201-07-4分子式:C8H12N4.Co分子量:223.14
材料名称:ZIF-67(Co)
其他名称:2-Methylimidazole Cobalt salt
CAS:46201-07-4
结构信息
单位分子式 C4H6N2.Co 单位分子量 223.14
配位金属 Co 配体 2-甲基咪唑(CAS:693-98-1)
孔径 0.34nm; 1.1nm 孔容 0.66 cm3/g
比表面 BET比表面1500 m2/g 
模拟结构       
产品性状
产品形貌 紫色粉末
Purple Powder
 
粒径 500nm-1um
稳定性
1) ZIF-67 空气中持久稳定,水相条件下不稳定
2)高热稳定性、热分解温度大于400℃
保存和活化方法
1) 常温或低温条件下,干燥密封保存
2)建议使用前120度(真空)烘箱活化5小时
其他特性
荧光:NA
应用领域
1) 储气材料和吸附材料
2) 可作为药物载体进行药物吸附和缓释
表征图谱
XRD
XRD-ZIF-67
BET
BET-ZIF-67
SEM
SEM-ZIF-67-3 s
SEM
SEM-ZIF-67-1 s
参考文献
1) H. Wu, X. Qian, H. Zhu, S. Ma, G. Zhu, Y. Long, RSC Adv. 2016, 6, 6915-6920, DOI: 10.1039/C5RA18557B ; Controlled synthesis of highly stable zeolitic imidazolate framework-67 dodecahedra and their use towards the templated formation of a hollow Co3O4 catalyst for CO oxidation;
2)Authors: Rahul R. Salunkhe, Jing Tang, Yuichiro Kamachi, Teruyuki Nakato, Jung Ho Kim, Yusuke Yamauchi; Publication information: ACS Nano, 2015, 9, 6;DOI: 10.1021/acsnano.5b01790; Asymmetric Supercapacitors Using 3D Nanoporous Carbon and Cobalt Oxide Electrodes Synthesized from a Single Metal-Organic Framework【文献解读】;
3)Lu Wang, Xiao Feng, Lantian Ren, Qiuhan Piao, Jieqiang Zhong, Yuanbo Wang, Haiwei Li, Yifa Chen, Bo Wang;Journal of the American Chemical Society, 2015, 137, 14;DOI 10.1021/jacs.5b01613;Flexible Solid-State Supercapacitor Based on a Metal−Organic Framework Interwoven by Electrochemically-Deposited PANI【文献解读】;
4) Daniel Saliba, Manal Ammar, Moustafa Rammal, Mazen Al-Ghoul, Mohamad Hmadeh;Journal of the American Chemical Society, 2018, 140, 5;DOI: 10.1021/jacs.7b11589;Crystal Growth of ZIF-8, ZIF-67, and Their Mixed-Metal Derivatives【文献解读】;
5) Yinyun Lu, Wenwen Zhan, Yue He, Yiting Wang, Xiangjian Kong, Qin Kuang, Zhaoxiong Xie, Lansun Zheng;ACS Applied Materials & Interfaces, 2014, 6, 4186-4195; DOI:10.1021/am405858v; MOF-Templated Synthesis of Porous Co₃O₄ Concave Nanocubes with High Specific Surface Area and Their Gas Sensing Properties【文献解读】;
6) Yinyun Lu, Yiting Wang, Hongli Li, Yuan Lin, Zhiyuan Jiang, Zhaoxiong Xie, Qin Kuang, Lansun Zheng;ACS Applied Materials & Interfaces, 2015, 7, 13604-13611; DOI:10.1021/acsami.5b03177;MOF-Derived Porous Co/C Nanocomposites with Excellent Electromagnetic Wave Absorption Properties【文献解读】;

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