材料名称：MIL-101(Fe)
其他名称：NA
CAS：1189182-67-9
其他名称：NA
CAS：1189182-67-9
结构信息
| 单位分子式 | C24O13ClFe3 | 单位分子量 | 699.237 | ||
| 配位金属 | Fe | 配体 | 对苯二甲酸（CAS：100-21-0） | ||
| 孔径 | 窗口: 1.2nm;孔径: 2.3-2.7nm | 孔容 | 1.8 cm3/g | ||
| 比表面 | BET比表面 2800 m2/g | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 红棕色粉末 |  |
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| 粒径 | 300-600nm | |||
稳定性
1) MIL-101(Fe)不宜久置会逐渐分解。在极性溶剂中会逐渐分解或转变构型，常规吸附用途建议在一周内使用测试完毕。
2) 高热稳定性、热分解温度大于300℃
2) 高热稳定性、热分解温度大于300℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2）建议使用前150度（真空）烘箱活化3小时
2）建议使用前150度（真空）烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 储气材料和吸附材料
2) 作为路易斯酸催化剂
2) 作为路易斯酸催化剂
表征图谱
参考文献
1）D. Lupu, O. Ardelean, G. Blanita, G. Borodi, M. D. Lazar, A. R. Biris, C. Ioan, M. Mihet, I. Misan, G. Popeneciu, Int. J. Hydrogen Energy 2011, 36, 3586, DOI: 10.1016/j.ijhydene.2010.12.043
2）Wang, D.; Huang, R.; Liu, W.; Sun, D.; Li, Z. ACS Catal. 2014, 4, 4254– 4260, DOI: 10.1021/cs501169t;
3) Qiying Xie, Yan Li, Zhaoling Lv, Hang Zhou, Xiangjun Yang, Jing Chen & Hong Guo; Sci Rep 7, 3316 2017; DOI:10.1038/s41598-017-03526-x; Effective Adsorption and Removal of Phosphate from Aqueous Solutions and Eutrophic Water by Fe-based MOFs of MIL-101【文献解读】；
3）Zhao, Meiting; Yuan, Kuo; Wang, Yun; Li, Guodong; Guo, Jun; Gu, Lin; Hu, Wenping; Zhao, Huijun; Tang, Zhiyong; Nature (2016), 538(7625), 495-499, DOI: 10.1038/nature19763 ; Metal–organic frameworks as selectivity regulators for hydrogenation reactions【文献解读】;
4) Dengke Wang, Renkun Huang, Wenjun Liu, Dengrong Sun, Zhaohui Li; ACS Catalysis, 2014, 4, 4254−4260; DOI: 10.1021/cs501169t ; Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways【文献解读】；
4) Dengke Wang, Renkun Huang, Wenjun Liu, Dengrong Sun, Zhaohui Li; ACS Catalysis, 2014, 4, 4254−4260; DOI: 10.1021/cs501169t ; Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways【文献解读】；
5）Dongbo Wang, Feiyue Jia, Hou Wang, Fei Chen, Ying Fang, Wenbo Dong, Guangming Zeng, Xiaoming Li, Qi Yang, Xingzhong Yuan. Journal of Colloid and Interface Science, 2018, 519, 1. DOI: 10.1016/j.jcis.2018.02.067. Simultaneously efficient adsorption and photocatalytic degradation of tetracycline by Fe-based MOFs.【文献解读】；
6）Feiping Zhao, Yongpeng Liu, Samia Ben Hammouda, Bhairavi Doshi, Néstor Guijarro, Xiaobo Min, Chong-Jian Tang, Mika Sillanpää, Kevin Sivula, Shaobin Wang. Applied Catalysis B: Environmental, 2020, 272, 119033. DOI: 10.1016/j.apcatb.2020.119033. MIL-101(Fe)/g-C3N4 for enhanced visible-light-driven photocatalysis toward simultaneous reduction of Cr(VI) and oxidation of bisphenol A in aqueous media.【文献解读】;
7）Huabin Zhang, Tao Wang, Junjie Wang, Huimin Liu, Thang Duy Dao, Mu Li, Guigao Liu, Xianguang Meng, Kun Chang, Li Shi, Tadaaki Nagao, Jinhua Ye. Advanced Materials, 2016, 28, 3703-3710. DOI: 10.1002/adma.201505187. Surface-Plasmon-Enhanced Photodriven CO₂ Reduction Catalyzed by Metal–Organic-Framework-Derived Iron Nanoparticles Encapsulated by Ultrathin Carbon Layers.【文献解读】;
8）Kowsalya Vellingiri, Pawan Kumar, Akash Deep, Ki-Hyun Kim. (2017). *Chemical Engineering Journal*, 307, 1116–1126. DOI: 10.1016/j.cej.2016.09.012. Metal-organic frameworks for the adsorption of gaseous toluene under ambient temperature and pressure.【文献解读】
9）Qiying Xie, Yan Li, Zhaoling Lv, Hang Zhou, Xiangjun Yang, Jing Chen, Hong Guo. Scientific Reports, 2017, 7, 1. DOI:10.1038/s41598-017-03526-x. Effective Adsorption and Removal of Phosphate from Aqueous Solutions and Eutrophic Water by Fe-based MOFs of MIL-101.【文献解读】
10) Zongchen Li, Xuemin Liu, Wei Jin, Qingsong Hu, Yaping Zhao. (2019). Journal of Colloid and Interface Science, 554, 692–704. DOI: 10.1016/j.jcis.2019.07.046. Adsorption behavior of arsenicals on MIL-101(Fe): The role of arsenic chemical structures.【文献解读】
11) Han Hu, Haixuan Zhang, Ya Chen, Yujia Chen, Li Zhuang, Huase Ou. Chemical Engineering Journal, 2019, 368. DOI: 10.1016/j.cej.2019.02.190. Enhanced photocatalysis degradation of organophosphorus flame retardant using MIL-101(Fe)/persulfate: Effect of irradiation wavelength and real water matrixes.【文献解读】
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