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4'-(3-吡啶基)-4,2':6',4'-三吡啶

6'-(4-pyridinyl)-3,4':2',4''-Terpyridine

CAS NO.:887917-77-3分子式:C20H14N4分子量:310.35196
产品名称:4'-​(3-​pyridyl)​-​4,​2':6',​4''-​terpyridine
其他名称:344-​pytpy;2,​6-​bis(4'-​pyridyl)​-​4-​(3'-​pyridyl)​pyridine
CAS:887917-77-3
结构信息
分子式 C20H14N4 分子量 310.35196
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Zn3(344-​pytpy)​2Cl6]​n [r3]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Smith, Christopher B.; Raston, Colin L.; Sobolev, Alexandre N.; Green Chemistry 2005, 7(9), 650-654, DOI: 10.1039/b507581p ; Poly(ethyleneglycol) (PEG)​: a versatile reaction medium in gaining access to 4'-​(pyridyl)​-​terpyridines
2) Samanta, Dipak; Mukherjee, Partha Sarathi; Chem.-Eur. J. 2014, 20(19), 5649-5656, DOI: 10.1002/chem.201305075 ; Structural Diversity in Multinuclear PdII Assemblies that Show Low-​Humidity Proton Conduction
3) Yang, Xiao-Le; Shangguan, Yi-Qing; Hu, Huai-Ming; Xu, Bing; Wang, Bao-Cheng; Xie, Juan; Yuan, Fei; Yang, Meng-Lin; Dong, Fa-Xin; Xue, Gang-Lin; J. Solid State Chem. 2014, 216, 13-22, DOI: 10.1016/j.jssc.2014.04.017 ; Synthesis, crystal structures and luminescent properties of zinc(II) metal-​organic frameworks constructed from terpyridyl derivative ligand
4) Karimi, Fatemeh; Yarie, Meysam; Zolfigol, Mohammad Ali; RSC Adv. 2020, 10(43), 25828-25835, DOI: 10.1039/d0ra04461j ; A convenient method for synthesis of terpyridines via a cooperative vinylogous anomeric based oxidation

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