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1,3,5,7-四(4-苯甲醛基)-金刚烷

1,3,5,7-tetrakis(4-formylphenyl)adamantane

CAS NO.:645401-15-6分子式:C38H32O4分子量:552.65828
产品名称:1,3,5,7-tetrakis(4-formylphenyl)adamantane
其他名称:TFPA;4,​4',​4'',​4'''-​Tricyclo[3.3.1.13,​7]​decane-​1,​3,​5,​7-​tetrayltetrakis[benz​aldehyde]
CAS:645401-15-6
结构信息
分子式 C38H32O4 分子量 552.65828
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料
2) 可用于合成 (DCFs) [r1];
3) 可用于合成 Polyaminal Networks:PAN-1 、PAN-2 [r2];
4) 可用于合成 porous poly(Schiff-base)s: PSN-DA, PSN-TAPB, PSN-TAPA, PSN-TAPM [r3]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Duncan, Nathan C.; Hay, Benjamin P.; Hagaman, Edward W.; Custelcean, Radu; Tetrahedron 2012, 68(1), 53-64, DOI: 10.1016/j.tet.2011.10.052 ; Thermodynamic, kinetic, and structural factors in the synthesis of imine-​linked dynamic covalent frameworks
2) Li, Guiyang; Zhang, Biao; Yan, Jun; Wang, Zhonggang; Macromolecules 2014, 47(19), 6664-6670, DOI: 10.1021/ma501497c ; Tetraphenyladamantane-​Based Polyaminals for Highly Efficient Captures of CO2 and Organic Vapors
3) Li, Guiyang; Zhang, Biao; Yan, Jun; Wang, Zhonggang; J. Mater. Chem. A 2014, 2(44), 18881-18888,DOI: 10.1039/C4TA04429K ; Micro- and mesoporous poly(Schiff-​base)​s constructed from different building blocks and their adsorption behaviors towards organic vapors and CO2 gas
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