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1,3,5-三(4-溴甲基苯基)苯

1,​3,​5-​Tris[(4-​bromomethyl)​phenyl]​benzene

CAS NO.:42837-44-5分子式:C27H21Br3分子量:585.16764
产品名称:1,​3,​5-​Tris[(4-​bromomethyl)​phenyl]​benzene
其他名称:TBMPB;4,​4''-​Bis(bromomethyl)​-​5'-​[4-​(bromomethyl)​phenyl]​-​1,​1':3',​1''-​terphenyl
CAS:42837-44-5
结构信息
分子式 C27H21Br3 分子量 585.16764
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为中间体用于合成MOF材料配体:
2) 可用于合成超支化聚苯[r2];
3) 可用于合成轮烷[r4];
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Voegtle, Fritz; Hohner, Gerd; Weber, Edwin; Chem. Commun. 1973, (11), 366-367, DOI: 10.1039/C39730000366 ; Novel multibridged macrocyclic systems
2) Kim, Young H.; Beckerbauer, Richard; Macromolecules (1994), 27(7), 1968-1971, DOI: 10.1021/ma00085a048 ; Role of End Groups on the Glass Transition of Hyperbranched Polyphenylene and Triphenylbenzene Derivatives
3) Zhang, Xue-Li; Guo, Cui-Ping; Yang, Qing-Yuan; Lu, Tong-Bu; Tong, Ye-Xiang; Su, Cheng-Yong; Chem. Mater. 2007, 19(19), 4630-4632, DOI: 10.1021/cm071767u ; Discrete Chiral Single-​Crystal Microtubes Assembled with Honeycomb Coordination Networks Showing Structural Diversity and Borromean Topology in One Single Crystal
4) Zhang, Ji-Na; Li, Hong; Zhou, Wei; Yu, Shi-Lin; Qu, Da-Hui; Tian, He; Chem.-Eur. J. 2013, 19(50), 17192-17200, DOI: 10.1002/chem.201303026 ; Fluorescence Modulation in Tribranched Switchable [4|Rotaxanes

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