产品名称：4-[4'-(2,2':6',2''-terpyridil]-boronic acid
其他名称：trpy-B(OH)2;Boronic acid, (4-[2,2':6',2''-terpyridin]-4'-ylphenyl)-; B-(4-[2,2':6',2''-Terpyridin]-4'-ylphenyl)boronic acid; 4'-(4-Boronatophenyl)-2,2':6',2''-terpyridine
CAS：381218-96-8
3) Wang, Jin-Liang; Li, Xiaopeng; Lu, Xiaocun; Hsieh, I-Fan; Cao, Yan; Moorefield, Charles N.; Wesdemiotis, Chrys; Cheng, Stephen Z. D.; Newkome, George R.; Journal of the American Chemical Society 2011, 133(30), 11450-11453, DOI: 10.1021/ja203645m ; Stoichiometric Self-Assembly of Shape-Persistent 2D Complexes: A Facile Route to a Symmetric Supramacromolecular Spoked Wheel
4) Li, Yiming; Jiang, Zhilong; Wang, Ming; Yuan, Jie; Liu, Die; Yang, Xiaoyu; Chen, Mingzhao; Yan, Jun; Li, Xiaopeng; Wang, Pingshan; 2016, 138(31), 10041-10046, DOI: 10.1021/jacs.6b06021 ; Giant, Hollow 2D Metalloarchitecture: Stepwise Self-Assembly of a Hexagonal Supramolecular Nut
其他名称：trpy-B(OH)2;Boronic acid, (4-[2,2':6',2''-terpyridin]-4'-ylphenyl)-; B-(4-[2,2':6',2''-Terpyridin]-4'-ylphenyl)boronic acid; 4'-(4-Boronatophenyl)-2,2':6',2''-terpyridine
CAS：381218-96-8
结构信息
| 分子式 | C21H16BN3O2 | 分子量 | 353.18164 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为中间体用于合成MOF材料配体：[Ru(trpy-B(OH)2)(tb2bpy)Cl](PF6) [r2]
表征图谱
参考文献
1) Aspley, Catherine J.; Williams, J. A. G.; New J. Chem. 2001, 25(9), 1136-1147, DOI: 10.1039/b103062k ; Palladium-catalysed cross-coupling reactions of ruthenium bis-terpyridyl complexes: strategies for the incorporation and exploitation of boronic acid functionality
2) Altobello, S.; Bignozzi, C. A.; Caramori, S.; Larramona, G.; Quici, Silvio; Marzanni, Giovanni; Lakhmiri, Rajae; J. Photochem. Photobio., A 2004), 166(1-3), 91-98, DOI: 10.1016/j.jphotochem.2004.04.029 ; Sensitization of TiO2 with ruthenium complexes containing boronic acid functions
