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[1,1':3',1''-Terphenyl]-3,3'',5,5''-tetracarboxylic acid, 5'-amino-

5-​amino-​3,​3,​5,​5-​tetracarboxylic acid

CAS NO.:2095221-49-9分子式:C22H15NO8分子量:421.3564
产品名称:5-​amino-​3,​3,​5,​5-​tetracarboxylic acid
其他名称:H4TTCA-​NH2; H4atta;5'-​Amino[1,​1':3',​1''-​terphenyl]​-​3,​3'',​5,​5''-​tetracarboxylic acid ; 2'-​amino-​[1,​1':4',​1"-​terphenyl]​-​3,​3",​5,​5"- tetracarboxylic acid
CAS:2095221-49-9
结构信息
分子式 C22H15NO8 分子量 421.3564
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:ZJU-​195(Cu) [r1]; [Co2(Hatta)​2·(H2O)​3] [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Zhang, Ling; Jiang, Ke; Li, Yanping; Zhao, Dian; Yang, Yu; Cui, Yuanjing; Chen, Banglin; Qian, Guodong; Cryst. Growth & Des. 2017, 17(5), 2319-2322, DOI: 10.1021/acs.cgd.7b00277 ; Microporous Metal-​Organic Framework with Exposed Amino Functional Group for High Acetylene Storage and Excellent C2H2​/CO2 and C2H2​/CH4 Separations
2) Sharma, Vivekanand; De, Dinesh; Saha, Ranajit; Das, Ranjita; Chattaraj, Pratim Kumar; Bharadwaj, Parimal K.; Chem. Commun. 2017, 53(100), 13371-13374, DOI: 10.1039/C7CC08315G ; A Cu(II)​-​MOF capable of fixing CO2 from air and showing high capacity H2 and CO2 adsorption
3) Sharma, Vivekanand; De, Dinesh; Bharadwaj, Parimal K.; Inorg. Chem. 2018, 57(14), 8195-8199, DOI: 10.1021/acs.inorgchem.8b00683 ; A Multifunctional Metal-​Organic Framework for Oxidative C-​O Coupling Involving Direct C-​H Activation and Synthesis of Quinolines
4) Saha, Ranajit; Sharma, Vivekanand; De, Dinesh; Bharadwaj, Parimal K.; Chattaraj, Pratim K.; Polyhedron 2018, 153, 254-260, DOI: 10.1016/j.poly.2018.07.048 ; A (T-​P) phase diagram for the adsorption​/desorption of carbon dioxide and hydrogen in a Cu(II)​-​MOF

5) Deng, Jia-Bin; Wang, Xin; Ni, Zi-Qiao; Zhu, Fei; Arabian J. Chem. 2020, 13(10), 7482-7489, DOI: 10.1016/j.arabjc.2020.08.023 ; Two Co(II)​-​based metal-​organic frameworks: Catalytic Knoevenagel condensation reactions and inhibitory activity on the scar tissue hyperplasia by reducing the activity of the VEGF signaling pathway

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