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1,3,5-Benzenetricarboxamide, N1,N3,N5-tri-3-pyridinyl-

1,3,5-Benzenetricarboxamide, N1,N3,N5-tri-3-pyridinyl-

CAS NO.:201036-79-5分子式:C24H18N6O3分子量:438.43812
产品名称:N,​N',​N''-​Tris(3-​pyridyl)​trimesic amide
其他名称:TPB ; 3-TPB;Tri-​3-​pyridinyl-​1,​3,​5-​benzenetricarboxamid​e; N,​N',​N''-​tris(3-​pyridinyl)​-​1,​3,​5-​benzenetricarboxamide
CAS:201036-79-5
结构信息
分子式 C24H18N6O3 分子量 438.43812
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Hydrogen-​bonded porous materials ; 分子笼 ; metal-​org. polyhedra (MOP); [CuI(aas-​TPB)​]​ [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Palmans, Anja R. A.; Vekemans, Jef A. J. M.; Meijer, E. W.; Palmans, Anja R. A.; Kooijman, Huub; Spek, Anton L.; Chem. Commun. 1997, (22), 2247-2248, DOI: 10.1039/a705339h ; Hydrogen-​bonded porous solid derived from trimesic amide
2) Moon, Dohyun; Kang, Sangmi; Park, Jaejoon; Lee, Kyungjae; John, Rohith P.; Won, Hosik; Seong, Gi Hun; Kim, Yang Sun; Kim, Ghyung Hwa; Rhee, Hakjune; Lah, Myoung Soo; Journal of the American Chemical Society 2006, 128(11), 3530-3531, DOI: 10.1021/ja060051h ; Face-​Driven Corner-​Linked Octahedral Nanocages: M6L8 Cages Formed by C3-​Symmetric Triangular Facial Ligands Linked via C4-​Symmetric Square Tetratopic PdII Ions at Truncated Octahedron Corners
3) Shi, Naien; Dong, Hao; Yin, Gui; Xu, Zheng; Li, Shuhua; Adv. Func. Mater. 2007, 17(11), 1837-1843, DOI: 10.1002/adfm.200600857 ; A smart supramolecular hydrogel exhibiting pH-​modulated viscoelastic properties
4) Park, Jaejoon; Hong, Seunghee; Moon, Dohyun; Park, Mira; Lee, Kyungjin; Kang, Sangmi; Zou, Yang; John, Rohith P.; Kim, Ghyung Hwa; Lah, Myoung Soo; Inorg. Chem. 2007, 46(24), 10208-10213, DOI: 10.1021/ic7013623 ; Porous Metal-​Organic Frameworks Based on Metal-​Organic Polyhedra with Nanosized Cavities as Supramolecular Building Blocks: Two-​Fold Interpenetrating Primitive Cubic Networks of [Cu6L8]​12+ Nanocages

5) Wang, Xiaolu; Liu, Mengjia; Wang, Yuqing; Fan, Hongyan; Wu, Jie; Huang, Chao; Hou, Hongwei; Inorg. Chem. 2017, 56(21), 13329-13336, DOI: 10.1021/acs.inorgchem.7b02106 ; Cu(I) Coordination Polymers as the Green Heterogeneous Catalysts for Direct C-​H Bonds Activation of Arylalkanes to Ketones in Water with Spatial Confinement Effect

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