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Pyridine, 2,2'-(1,3-phenylene)bis-

Pyridine, 2,2'-(1,3-phenylene)bis-

CAS NO.:136538-84-6分子式:C16H12N2分子量:232.27988
产品名称:1,​3-​Di(2-​pyridyl)​benzene
其他名称:DPBH;2,​2'-​(1,​3-​Phenylene)​bis[pyridine]​; 1,​3-​Bis(2-​pyridinyl)​benzene; 1,​3-​Bis(2-​pyridyl)​benzene;
CAS:136538-84-6
结构信息
分子式 C16H12N2 分子量 232.27988
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Ru(tterpy)​(dpb)​ [r1]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Beley, Marc; Collin, Jean Paul; Louis, Remy; Metz, Bernard; Sauvage, Jean Pierre; J. Am. Chem. Soc. 1991, 113(22), 8521-8522, DOI: 10.1021/ja00022a049 ; 3,​3',​5,​5'-​Tetrapyridylbiphenyl, a bis-​cyclometalating bridging ligand with a high coupling ability in ruthenium(III)​, ruthenium(II) mixed valence systems
2) Cardenas, Diego J.; Echavarren, Antonio M.; Ramirez de Arellano, M. Carmen; Organometallics 1999, 18(17), 3337-3341, DOI: 10.1021/om990125g ; Divergent Behavior of Palladium(II) and Platinum(II) in the Metalation of 1,​3-​Di(2-​pyridyl)​benzene
3) Williams, J. A. Gareth; Beeby, Andrew; Davies, E. Stephen; Weinstein, Julia A.; Wilson, Claire; Inorg. Chem. 2003, 42(26), 8609-8611, DOI: 10.1021/ic035083+ ; An Alternative Route to Highly Luminescent Platinum(II) Complexes: Cyclometalation with N-​C-​N-​Coordinating Dipyridylbenzene Ligands
4) Soro, Barbara; Stoccoro, Sergio; Minghetti, Giovanni; Zucca, Antonio; Cinellu, Maria Agostina; Gladiali, Serafino; Manassero, Mario; Sansoni, Mirella; Organometallics 2005, 24(1), 53-61, DOI: 10.1021/om040102o ; Synthesis of the First C-​2 Cyclopalladated Derivatives of 1,​3-​Bis(2-​pyridyl)​benzene. Crystal Structures of [Hg(N-​C-​N)​Cl]​, [Pd(N-​C-​N)​Cl]​, and [Pd2(N-​C-​N)​2(μ-​OAc)​]​2[Hg2Cl6]​. Catalytic Activity in the Heck Reaction

5) Kletsch, Lukas; Hoerner, Gerald; Klein, Axel; Organometallics 2020, 39(15), 2820-2829, DOI: 10.1021/acs.organomet.0c00355 ; Cyclometalated Ni(II) Complexes [Ni(N[symbol omitted]​C[symbol omitted]​N)​X] of the Tridentate 2,​6-​di(2-​pyridyl)​phenide Ligand

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