+86-21-51987688
首页 > 产品目录 > MOF材料有机配体 > 羧酸MOF配体 > 二元羧酸MOF配体 > 对苯二甲酸型配体

1,4-Benzenedicarboxylic acid, 2,5-bis(2-methoxyethoxy)-

1,4-Benzenedicarboxylic acid, 2,5-bis(2-methoxyethoxy)-

CAS NO.:1265529-85-8分子式:C14H18O8分子量:314.28792
产品名称:2,​5-​Bis(2-​methoxyethoxy)​terephthalic acid
其他名称:H2BME-​bdc; H2BDC-​2OEtOMe;2,​5-​Bis(2-​methoxyethoxy)​-​1,​4-​benzenedicarboxylic acid
CAS:1265529-85-8
结构信息
分子式 C14H18O8 分子量 314.28792
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:M2(BME-​bdc)​2(dabco) (M2+ = Zn2+, Co2+, Ni2+, Cu2+) [r1]; UIO-66-​2OEtOMe [r4]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Henke, Sebastian; Schmid, Rochus; Grunwaldt, Jan-Dierk; Fischer, Roland A.; Chem.-Eur. J. 2010, 16(48), 14296-14306, DOI: 10.1002/chem.201002341 ; Flexibility and Sorption Selectivity in Rigid Metal-​Organic Frameworks: The Impact of Ether-​Functionalised Linkers
2) Henke, Sebastian; Fischer, Roland A.; J. Am. Chem. Soc. 2011, 133(7), 2064-2067, DOI: 10.1021/ja109317e ; Gated Channels in a Honeycomb-​like Zinc-​Dicarboxylate-​Bipyridine Framework with Flexible Alkyl Ether Side Chains
3) Schneemann, Andreas; Vervoorts, Pia; Hante, Inke; Tu, Min; Wannapaiboon, Suttipong; Sternemann, Christian; Paulus, Michael; Wieland, D. C. Florian; Henke, Sebastian; Fischer, Roland A.; Chem. Mater 2018, 30(5), 1667-1676, DOI: 10.1021/acs.chemmater.7b05052 ; Different Breathing Mechanisms in Flexible Pillared-​Layered Metal-​Organic Frameworks: Impact of the Metal Center
4) Fast, Caleb D.; Woods, Jason; Lentchner, Jared; Makal, Trevor A.; Dalton Trans. 2019, 48(39), 14696-14704,DOI: 10.1039/c9dt03004b ; Stabilizing defects in metal-​organic frameworks: pendant Lewis basic sites as capping agents in UiO-​66-​type MOFs toward highly stable and defective porous materials

相关产品

13064-64-7
1293386-03-4
13064-64-7
128834-29-7
123415-45-2
123440-34-6
132720-81-1