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1,3,5-三(3,5-二羧基苯基乙炔基)苯

1,3,5-tris(3,5-dicarboxyphenylethynyl)benzene

CAS NO.:1173285-13-6分子式:C36H18O12分子量:642.52092
产品名称:1,​3,​5-​tris(3,​5-​dicarboxylphenylethynyl)​benzene
其他名称:btei;5,5′,5′′-benzene-1,3,5-triyltris(1-ethynyl-2-isophthalate)
CAS:1173285-13-6
结构信息
分子式  C36H18O12 分子量 642.52 
性状照片  
性质说明
1) 1173285-13-6 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:PCN-61 [r1]; PMOF-​2(Zn) [r4]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Zhao, D.; Yuan, D.; Sun, D.; Zhou, H.; J. Am. Chem. Soc. 2009, 131, 26, 9186-9188, DOI: 10.1021/ja901109t ; Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows  
2) Zheng, B.; Bai, J.; Duan, J.; Wojtas, L.; Zaworotko, M.; J. Am. Chem. Soc. 2011, 133, 4, 748-751, DOI: 10.1021/ja110042b ; Enhanced CO2 Binding Affinity of a High-Uptake rht-Type Metal−Organic Framework Decorated with Acylamide Groups  
3) Song, X.; Jeong, S.; Kim, D.; Lah, M.; CrystEngComm 2012, 14(18), 5753-5756, DOI: DOI:10.1039/c2ce26115d ; Transmetalations in two metal–organic frameworks with different framework flexibilities: Kinetics and core–shell heterostructure 
4) Hong, S.; Oh, M.; Park, M.; Yoon, J.; Chang, J.; Lah, M.; Chem. Commun. 2009, 36, 5397-5399, DOI: 10.1039/B909250A ; Large H2 storage capacity of a new polyhedron-​based metal-​organic framework with high thermal and hygroscopic stability
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