产品名称： Hexaethynylbenzene （六乙炔基苯不稳定，易发生氧化或关环反应。建议参考选购100516-62-9，脱硅烷后原位反应。）
其他名称： HEB ; Benzene, hexaethynyl-; 1,2,3,4,5,6-Hexaethynylbenzene ; 六乙炔基苯
CAS： 100516-61-8
其他名称： HEB ; Benzene, hexaethynyl-; 1,2,3,4,5,6-Hexaethynylbenzene ; 六乙炔基苯
CAS： 100516-61-8
结构信息
| 分子式 | C18H6 | 分子量 | 222.24024 | ||
| 性状照片 | |||||
性质说明
1) 溶于DCM、DMF、DMSO等
2) 2-8℃ 密封保存
2) 2-8℃ 密封保存
合成应用
1) 作为单体前驱体合成石墨炔材料 [r4, r5]
2) 可作为单体用于合成 phenylenes [r3]等材料
表征图谱
参考文献
1) Diercks, Rainer; Armstrong, James C.; Boese, Roland; Vollhardt, K. Peter C.; Angew. Chem. 1986, 98(3), 270-271, Hexaethynylbenzene
2) Neenan, Thomas X.; Whitesides, George M.; J. Org. Chem. 1988, 53(11), 2489-2496, DOI: 10.1021/jo00246a018 ; Synthesis of high carbon materials from acetylenic precursors. Preparation of aromatic monomers bearing multiple ethynyl groups
3) Holmes, Daniel; Kumaraswamy, Sriram; Matzger, Adam J.; Vollhardt, K. Peter C.; Chem.-Eur. J. 1999, 5(11), 3399-3412, DOI: 10.1002/(SICI)1521-3765(19991105)5:11<3399::AID-CHEM3399>3.0.CO;2-V ; On the nature of nonplanarity in the [N]phenylenes
4) Huang, Changshui; Zhang, Shengliang; Liu, Huibiao; Li, Yongjun; Cui, Guanglei; Li, Yuliang; Nano Energy 2015, 11, 481-489, DOI: 10.1016/j.nanoen.2014.11.036 ; Graphdiyne for high capacity and long-life lithium storage
5) Zhou, Jingyuan; Gao, Xin; Liu, Rong; Xie, Ziqian; Yang, Jin; Zhang, Shuqing; Zhang, Gengmin; Liu, Huibiao; Li, Yuliang; Zhang, Jin; Liu, Zhongfan; J. Am. Chem. Soc. 2015, 137(24), 7596-7599, DOI: 10.1021/jacs.5b04057 ; Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction
6) Gao, Xin; Zhou, Jingyuan; Du, Ran; Xie, Ziqian; Deng, Shibin; Liu, Rong; Liu, Zhongfan; Zhang, Jin; Adv. Mater. 2016, 28(1), 168-173, DOI: 10.1002/adma.201504407 ; Robust Superhydrophobic Foam: A Graphdiyne-Based Hierarchical Architecture for Oil/Water Separation
